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The macroscopic state of a system is characterized by a distribution on the microstates.The entropy of this distribution is given by the Gibbs entropy formula, named after J. Willard Gibbs.For a classical system (i.e., a collection of classical particles) with a discrete set of microstates, if is the energy of microstate i, and is the probability that it occurs during ... On the Second Law of Thermodynamics. Introduction; The Second Law of Thermodynamics (In Classical Thermodynamics) ; A New Concept: Phase Space vs Coordinate Space; The Second Law of Thermodynamics (In Statistical Mechanics, I) ; The Paradox of Irreversibility The law of entropy, or the second law of thermodynamics, along with the first law of thermodynamics comprise the most fundamental laws of physics. 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