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This chapter discusses chiral metal atoms in optically active organo-transition-metal compounds. An important approach to stereochemical problems is to make use of the concept of chirality. The chiral center most frequently encountered is the asymmetric carbon atom––a tetrahedral C atom––bonded to four different substituents. Lecture 5 - Stereochemistry in Transition Metal Complexes ... Budotitaneis an anticancer agent that is active against a number of tumors but best at reducing the size of colon/rectal tumors. ... Thus this complex is exactly analogous to carbon compounds. 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